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Petroleum Science >2018,??Issue 4:??890-897 DOI:

Synthesis of amphiphilic peroxophosphomolybdates for oxidative desulfurization of fuels in ionic liquids Open?Access

文章信息

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作者：Beibei Zhang, Wei Jiang, Xiaonan Fan, Ming Zhang, Yanchen Wei, Jing He, Changfeng Li, Huaming Li and Wenshuai Zhu
作者單位：

School of Energy and Power Engineering, Jiangsu University, Zhenjiang 212013, People’s Republic of China; School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng 224051, People’s Republic of China,Institute for Energy Research, Jiangsu University, Zhenjiang 212013, Jiangsu, People’s Republic of China,School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, People’s Republic of China,Institute for Energy Research, Jiangsu University, Zhenjiang 212013, Jiangsu, People’s Republic of China,School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, People’s Republic of China,School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, People’s Republic of China,School of Energy and Power Engineering, Jiangsu University, Zhenjiang 212013, People’s Republic of China,Institute for Energy Research, Jiangsu University, Zhenjiang 212013, Jiangsu, People’s Republic of China and School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, People’s Republic of China

投稿時間：2018-04-14
引用方式：

文章摘要

Three amphiphilic peroxophosphomolybdates [C4mim]3PMo4O24, [C8mim]3PMo4O24 and [C16mim]3PMo4O24 were synthesized and characterized. These catalysts were used for extraction and catalytic oxidative desulfurization of fuel with H2O2 as an oxidant and ionic liquid [C4mim]BF4 as an extractant. It was found that [C16mim]3PMo4O24 showed the highest catalytic activity and the sulfur content could decrease to 7.5 ppm. In contrast, the desulfurization system shows very low performance without H2O2 or ionic liquid. The detailed reaction conditions were optimized including reaction time, temperature, the dosage of H2O2 and catalyst, and different sulfur compounds. After the reaction, the catalysts and the ionic liquid can be cycled 8 times with a little decrease in desulfurization efficiency.

關鍵詞

    Peroxophosphomolybdate, Oxidative desulfurization, Ionic liquid, H2O2