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Petroleum Science >2017,??Issue 3:??605-615 DOI: https://doi.org/10.1007/s12182-017-0178-x

Efficient ozonation of reverse osmosis concentrates from petroleum refinery wastewater using composite metal oxideloaded alumina Open?Access

文章信息

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作者：Yu Chen, Chun-Mao Chen, Brandon A. Yoza, Qing X. Li, Shao-Hui Guo, Ping Wang, Shi-Jie Dong and Qing-Hong Wang
作者單位：

State Key Laboratory of Petroleum Pollution Control, Beijing Key Laboratory of Oil and Gas Pollution Control, China University of Petroleum, Beijing 102249, China,State Key Laboratory of Petroleum Pollution Control, Beijing Key Laboratory of Oil and Gas Pollution Control, China University of Petroleum, Beijing 102249, China,Hawaii Natural Energy Institute, University of Hawaii at Manoa, Honolulu, HI 96822, USA,Department of Molecular Biosciences and Bioengineering, University of Hawaii at Manoa, Honolulu, HI 96822, USA,State Key Laboratory of Petroleum Pollution Control, Beijing Key Laboratory of Oil and Gas Pollution Control, China University of Petroleum, Beijing 102249, China,State Key Laboratory of Petroleum Pollution Control, Beijing Key Laboratory of Oil and Gas Pollution Control, China University of Petroleum, Beijing 102249, China,State Key Laboratory of Petroleum Pollution Control, Beijing Key Laboratory of Oil and Gas Pollution Control, China University of Petroleum, Beijing 102249, China and State Key Laboratory of Petroleum Pollution Control, Beijing Key Laboratory of Oil and Gas Pollution Control, China University of Petroleum, Beijing 102249, China

投稿時間：2016-12-15
引用方式：Chen, Y., Chen, CM., Yoza, B.A. et al. Pet. Sci. (2017) 14: 605. https://doi.org/10.1007/s12182-017-0178-x

文章摘要

Novel Mn–Fe–Mg- and Mn–Fe–Ce-loaded alumina (Mn–Fe–Mg/Al2O3 and Mn–Fe–Ce/Al2O3) were developed to catalytically ozonate reverse osmosis concentrates generated from petroleum refinery wastewaters (PRW-ROC). Highly dispersed 100–300-nm deposits of composite multivalent metal oxides of Mn (Mn2+, Mn3+, and Mn4+), Fe (Fe2+ and Fe3+) and Mg (Mg2+), or Ce (Ce4+) were achieved on Al2O3 supports. The developed Mn–Fe–Mg/Al2O3 and Mn–Fe–Ce/Al2O3 exhibited higher catalytic activity during the ozonation of PRW-ROC than Mn–Fe/Al2O3, Mn/Al2O3, Fe/Al2O3, and Al2O3. Chemical oxygen demand removal by Mn–Fe–Mg/Al2O3- or Mn– Fe–Ce/Al2O3-catalyzed ozonation increased by 23.9% and 23.2%, respectively, in comparison with single ozonation. Mn–Fe–Mg/Al2O3 and Mn–Fe–Ce/Al2O3 notably promoted OH generation and OH-mediated oxidation. This study demonstrated the potential use of composite metal oxide-loaded Al2O3 in advanced treatment of bio-recalcitrant wastewaters.

關鍵詞

    Petroleum refinery wastewater, Reverse osmosis concentrate, Catalytic ozonation, Composite metal oxide